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Rare-earth mineral series

Wakefieldite

Wakefieldite
All data from the card 16
Category
Rare-earth mineral
Formula
((La,Ce,Nd,Y)VO4)
IMA symbol
Wf
Strunz classification
8.AD.35
Crystal system
Tetragonal
Crystal class
Ditetragonal dipyramidal (4/mmm) H-M symbol: (4/m 2/m 2/m)
Space group
I41/amd
Color
Canary-yellow, pale tan (Wakefieldite-(Y)); Dark red to coal-black, pale yellow to bluish gray (Wakefieldite-(Ce)); Light pink, brown (Wakefieldite-(La)
Crystal habit
Prismatic crystals, pulverulent masses
Cleavage
Good on {100}
Tenacity
Very brittle
Mohs scale hardness
4–5
Diaphaneity
Translucent to opaque
Specific gravity
4.25 (calculated Wakefieldite-(Y)); 4.74 (meas. Wakefieldite-(Ce)
Optical properties
Uniaxial (+)
Refractive index
nω = 2.000, nε = 2.140

Wakefieldite ((La,Ce,Nd,Y)VO4) is an uncommon rare-earth element vanadate mineral. There are four main types described of wakefieldite- wakefieldite-(La), wakefieldite-(Ce), wakefieldite-(Nd), and wakefieldite-(Y), depending upon the dominant rare-earth metal ion present. Wakefieldite has a Mohs hardness ranging from 4 to 5. Wakefieldite forms crystals of tetragonal structure. In terms of crystal structure, it is the vanadate analog of the rare-earth phosphate mineral xenotime. Unlike xenotime, it is more favorable for wakefieldite to contain the lighter rare-earth elements over the heavier ones. Due to the lanthanide contraction, the heavier rare earths have smaller ionic radii than the lighter ones. When the phosphate anion is replaced by the larger vanadate anion, the tetragonal crystal system preferentially accommodates the larger light rare-earth elements.

Wakefieldite was first described for an occurrence in the Evans Lou mine, St. Pierre de Wakefield, Quebec, Canada and later designated Wakefieldite-(Y).

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Text from Wikipedia, CC BY-SA 4.0 · Source article