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Fatty portion of milk

Butterfat

Butterfat

Butterfat or milkfat is the fatty portion of milk. Milk and cream are often sold according to the amount of butterfat they contain.

Composition

Structure of a triglyceride containing myristic, palmitic, and oleic acid
Structure of a triglyceride containing myristic, palmitic, and oleic acid

Butterfat is mainly composed of triglycerides. Each triglyceride contains three fatty acids. Butterfat triglycerides contain the following amounts of fatty acids (by mass fraction):

Fatty acid content of butterfat
Type of fatty acid pct
Lower saturated (at most C12)
 
11%
Myristic saturated C14
 
12%
Palmitic saturated C16
 
31%
Stearic saturated C18
 
11%
Palmitoleic monounsaturated C16:1
 
4%
Oleic monounsaturated C18:1
 
24%
Linoleic polyunsaturated C18:2
 
3%
Alpha-Linolenic polyunsaturated C18:3
 
1%
Trans (mainly vaccenic C18:1 trans-11)
 
3%
black: Saturated; grey: Monounsaturated; green: Polyunsaturated; blue: Trans

Butterfat contains about 3% trans fat, which is slightly less than 0.5 grams per US tablespoon. Trans fats occur naturally in meat and milk from ruminants. The predominant kind of trans fat found in milk is vaccenic fatty acid. Trans fats may be also found in some industrially produced foods, such as shortenings obtained by hydrogenation of vegetable oils. In light of recognized scientific evidence, nutritional authorities consider all trans fats equally harmful for health and recommend that their consumption be reduced to trace amounts. However, two Canadian studies have shown that vaccenic acid could be beneficial compared to vegetable shortenings containing trans fats, or a mixture of pork lard and soy fat, by lowering total LDL and triglyceride levels. A study by the US Department of Agriculture showed that vaccenic acid raises both HDL and LDL cholesterol, whereas industrial trans fats only raise LDL with no beneficial effect on HDL.

Butterfat contains 3 to 4% tributyrin, a triglyceride (fat) and precursor of the short-chain fatty acid butyric acid, and is the richest-known food source of tributyrin.

Milk fatty acids, length, and position on glycerol (1, 2, 3)
Fatty acid length mol%
(rounded)
1 2 3
Butyryl C4 12 0 0 100
Caproyl C6 5 0 7 93
Caprylyl C8 2 25 12 63
Capryl C10 4 17 27 56
Lauryl C12 4 42 53 5
Myristyl C14 11 29 52 19
Palmityl C16 24 47 45 8
Hexadecenoyl C16:1 3 36 46 18
Stearyl C18 7 49 45 6
Oleyl C18:1 24 42 26 32
Linoleyl C18:2 3 23 47 31

Standards

Most countries have standards for minimum fat levels in dairy products.

United States

In the U.S., there are federal standards for butterfat content of dairy products.

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Text from Wikipedia, CC BY-SA 4.0 · Source article